Session: High-Temperature Materials and Corrosion Evaluation and Mitigation
An enhanced UNS S44400 (K44M) Ferritic Stainless Steel Grade for CH4-H2 Burner Application (C2026-00095)
Thursday, March 19, 2026
9:00 AM - 9:30 AM Central
Location: 361 DE
Earn .5 PDH
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K44M, a ferritic stainless steel, improves upon UNS S44400 with 19%-wt. Chromium, niobium, and molybdenum, omitting titanium. Designed for applications up to 1000°C, it boasts superior high-temperature mechanical properties, wet corrosion, and cyclic oxidation resistance. Its high-temperature performance and cost-effectiveness make it ideal for H2-blended CH4 burners. This paper will detail the grade's wet and hot corrosion resistance, highlighting benefits of high-temperature pre-treatment (>700°C) and the advantage of higher chromium for severe corrosion at ~600°C. While 950°C oxidation is slightly faster than alumina-forming grades, it's parabolic and not a long-term issue. The paper also explores hydrogen's impact on oxidation, noting K44M's superior resistance in H2 or mixed H2/H2O-O2 atmospheres due to high chromium and molybdenum. Fabrication mirrors UNS S44100 (forming, welding), with easier brazing due to no titanium. K44M's improved high-temperature properties, corrosion resistance, and ease of fabrication make it an excellent alternative to alumina-forming ferritics for burner applications, with a lifespan exceeding 15 years.